The primary purpose of matte smelting is to melt and recombine the charge into a homogeneous matte of metallic copper, nickel, cobalt, and iron sulfides and to give an iron and silicon oxide slag. It is done in many types of furnace on both roasted or unroasted sulfide feed material.

The reverberatory furnace is essentially a rectangular refractory-brick box equipped with end-wall burners to provide heat for melting. The furnace is relatively quiet, and it does not blow out much fine feed (which is added through roof ports) with the exhaust gases. The matte is tapped periodically from a centre taphole, while the slag runs off continuously at the furnace flue end. Oxygen lances inserted through the roof, or oxygen added through the burners, can increase smelting capacity considerably.

Electric furnaces are similar to reverberatory furnaces except for the method of heating—in this case a row of electrodes projecting through the roof into the slag layer on the furnace hearth and heating by resistance.

Flash smelting is a relatively recent development that has found worldwide acceptance. It is an autogenous process, using the oxidation of sulfides in an unroasted charge to supply the heat required to reach reaction temperatures and melt the feed material. The most widely used furnace has a vertical reaction shaft at one end of a long, low settling hearth and a vertical gas-uptake shaft at the other end. Fine, unroasted feed is blown into the reaction shaft along with preheated air; these react instantaneously, and liquid droplets fall onto the settling hearth, separating into layers of slag and matte. The off-gas, high in sulfur dioxide, is ideal for sulfur-recovery processes.

The second stage of matte smelting is converting the sulfides to metal. For many years the standard vessel for this operation has been the Peirce-Smith converter. This is a rotatable, refractory-lined, horizontal steel drum with an opening at the centre of the top for charging and discharging and a row of tuyeres across the back through which air, oxygen-enriched air, or oxygen can be blown into the liquid bath. Molten matte from the smelting furnace is poured into the converter, after which gas is blown through the tuyeres to oxidize first iron and then sulfur. The sulfur goes off as sulfur dioxide gas and the iron as iron oxide slag, leaving semipure metal. Considerable heat is generated by this exothermic reaction, keeping the bath liquid and maintaining the required reaction temperature.

More recent processes take advantage of exothermic heat evolution to accomplish both the smelting of unroasted sulfides and the conversion of matte in one combined operation. These are the Noranda, TBRC (top-blown rotary converter), and Mitsubishi processes. The Noranda reactor is a horizontal cylindrical furnace with a depression in the centre where the metal collects and a raised hearth at one end where the slag is run off. Pelletized unroasted sulfide concentrate is poured into the molten bath at one end, where tuyeres inject an air-oxygen mixture. This causes an intense mixing action that aids the melting, smelting, and oxidation steps, which follow one another in sequence, by taking advantage of the exothermic heat. The TBRC also is cylindrical in shape but is inclined at 17° to the horizontal, has an open mouth at the high end for charging and pouring, and revolves at 5 to 40 rotations per minute. A lance inserted through the mouth can give any combination of oxygen, air, or natural gas to impinge on the molten bath and create the conditions required for smelting and oxidizing. The combination of surface blowing and bath rotation improves the performance of the converter. The Mitsubishi process is a continuous smelting-converting operation that uses three stationary furnaces in series. The first furnace is for smelting, with oxygen lances and a fuel-fired burner inserted through the roof. Slag and matte flow from here to a slag-cleaning furnace (heated by electric arc), and high-grade matte flows from this to the converting furnace, where oxygen-enriched air is blown into the bath through roof lances. Exothermic heat produced here is sufficient to keep the bath up to reaction temperature.

Electrolytic smelting

Smelting is also carried out by the electrolytic dissociation, at high temperatures, of a liquid metallic chloride compound (as is done with magnesium) or of a metallic oxide powder dissolved in molten electrolyte (as is done with aluminum). In each case, electric current is passed through the bath to dissociate the metallic compound; the metal released collects at the cathode, while a gas is given off at the anode.

The magnesium smelting cell consists of a steel pot that serves as the cathode; two rows of graphite electrodes are inserted through a refractory cover as anodes. The electrolyte is a mixture of chlorides, with magnesium chloride making up 20 percent, and the cell is maintained at 700 °C (1,300 °F). The passage of current breaks down the magnesium chloride into chlorine gas and magnesium metal, which go to the anode and cathode, respectively.

In the Hall-Héroult smelting process, a nearly pure aluminum oxide compound called alumina is dissolved at 950 °C (1,750 °F) in a molten electrolyte composed of aluminum, sodium, and fluorine; this is electrolyzed to give aluminum metal at the cathode and oxygen gas at the anode. The smelting cell is a carbon-lined steel box, which acts as the cathode, and a row of graphite electrodes inserted into the bath serves as anodes.